|
|
Essential papers
|
|
Most important publications in key research interests:
+ [3+2] cycloaddition reactions
+ Diels-Alder / Hetero Diels-Alder reactions
+ Sigmatropic rearrangements
+ Thermal eliminations
+ Synthesis of conjugated nitroalkenes and their pharmaceutical applications
+ Ionic liquids and their application in organic synthesis
+ Kinetic aspects of cycloaddition reactions
|
|
|
|
|
[3+2] cycloaddition reactions
|
|
|
|
 |
|
On the question of zwitterionic intermediates in the [3+2] cycloaddition reactions: A critical review
Jasinski R., Dresler E..
Organics, 1, 49 (2020) |
|
|
|
|
|
|
Clean and molecularly programmable protocol for preparation of bis-heterobiarylic systems via a domino pseudocyclic reaction as a valuable alternative for TM-catalyzed cross-couplings
Wolinski P., Kacka-Zych A., Demchuk O.M., Lapczuk-Krygier A., Miroslaw B., Jasinski R.
Journal of Cleaner Production, 275, 122086 (2020) |
|
|
|
|
|
|
A new insight on the molecular mechanism of the reaction between (Z)-C,N-diphenylnitrone and 1,2-bismethylene-3,3,4,4,5,5-hexamethylcyclopentane
Jasinski R.,
Journal of Molecular Graphics and Modelling, 94, 107461 (2020) |
|
|
|
|
|
|
A DFT Study on the Barton-Kellogg Reaction - The Molecular Mechanism of the Formation of Thiiranes in the Reaction between Diphenyldiazomethane and Diaryl Thioketones
Mloston G., Jasinski R., Kula K., Heimgartner H.
European Journal of Organic Chemistry, 176-182 (2020) |
|
|
|
|
|
|
Experimental and Computational Studies on Stepwise [3+2]-Cycloadditions of Diaryldiazomethanes with Electron-Deficient Dimethyl (E)- and (Z)-2,3-Butenedioates
Mloston G., Celeda M., Jasinski R., Heimgartner H.
European Journal of Organic Chemistry, 422-431 (2019) |
|
|
|
|
|
|
The structural aspects of the transformation of 3-nitroisoxazoline-2-oxide to 1-aza-2,8-dioxabicyclo[3.3.0]octane derivatives: experimental and MEDT theoretical study
Wolinski P., Kacka-Zych A., Dziuk B., Ejsmont K., Lapczuk-Krygier A., Dresler E.
Journal of Molecular Structure, 1192, 27-34 (2019) |
|
|
|
|
|
|
Regiospecific formation of the nitromethyl-substituted 3-phenyl-4,5-dihydroisoxazole via [3+2] cycloaddition
Miroslaw B., Babyuk D., Lapczuk-Krygier A., Kacka A., Demchuk O., Jasinski R.,
Monatshefte fur Chemie - Chemical Monthly, 149, 1877-1884 (2018) |
|
|
|
|
|
|
A DFT computational study on molecular mechanism of [3+2] cycloaddition reactions between nitroethene and benzonitrile N-oxides
Jasinski R., Jasinska E., Dresler E.
Journal of Molecular Modeling, 23, 13 (2017) |
|
|
|
|
|
|
Unexpected course of reaction between (E)-2-aryl-1-cyano-1-nitroethenes and diazafluorene: why is there no 1,3-dipolar cycloaddition?
Jasinski R., Kula K., Kacka A., Miroslaw B.
Monatshefte fur Chemie - Chemical Monthly, 148, 909-915 (2017) |
|
|
|
|
|
|
A unique example of non-catalyzed [3+2] cycloaddition involving (2E)-3-aryl-2-nitroprop-2-enenitriles
Zmigrodzka M., Dresler E., Hordyjewicz-Baran Z., Kulesza R., Jasinski R.
Chemistry of Heterocyclic Compounds, 53, 1161-1162 (2017) |
|
|
|
|
|
|
Experimental and theoretical DFT study on synthesis of sterically crowded 2,3,3,(4)5-tetrasubstituted-4-nitroisoxazolidines via 1,3-dipolar cycloaddition reactions between ketonitrones and conjugated nitroalkenes
Jasinski R., Mroz K., Kacka A.
Journal of Heterocyclic Chemistry, 53, 1424-1429 (2016) |
|
|
|
|
|
|
In the searching for zwitterionic intermediates on reaction paths of [3+2] cycloaddition reactions between 2,2,4,4-tetramethyl-3-thiocyclobutanone S-methylide and polymerizable olefins
Jasinski R.
RSC Advances, 5, 101045-101048 (2015) |
|
|
|
|
|
|
Diels-Alder / Hetero Diels-Alder reactions
|
|
|
|
|
|
Molecular mechanism of Hetero Diels-Alder reactions between (E)-1,1,1-trifluoro-3-nitrobut-2-enes and enamine systems in the light of Molecular Electron Density Theory
Kacka-Zych A., Jasinski R.
Journal of Molecular Graphics and Modelling, 101, 107714 (2020) |
|
|
|
|
|
|
B-Trifluoromethylated nitroethenes in Diels-Alder reaction with cyclopentadiene: A DFT computational study
Jasinski R.
Journal of Fluorine Chemistry, 206, 1-7 (2018) |
|
|
|
|
|
|
One-step versus two-step mechanism of Diels-Alder reaction of 1-chloro-1-nitroethene with cyclopentadiene and furan
Jasinski R.
Journal of Molecular Graphics and Modelling 75, 55-61 (2017) |
|
|
|
|
|
|
A reexamination of molecular mechanism of Diels-Alder reaction between tetrafluoroethene and cyclopentadiene
Jasinski R.
Reaction Kinetics, Mechanisms and Catalysis, 119, 49-57 (2016) |
|
|
|
|
|
|
Searching for zwitterionic intermediates in Hetero Diels-Alder reactions between methyl a,p-dinitrocinnamate and vinyl-alkyl ethers
Jasinski R.
Computational and Theoretical Chemistry, 1046, 93-98 (2014) |
|
|
|
|
|
|
An experimental and theoretical study of the hetero Diels-Alder reactions between (E)-2-aryl-1-cyano-1-nitroethenes and ethyl vinyl ether: one-step or zwitterionic, two-step mechanism?
Jasinski R., Kubik M., Lapczuk-Krygier A., Kacka A., Dresler E., Boguszewska-Czubara A.
Reaction Kinetics, Mechanisms and Catalysis, 113, 333-345 (2014) |
|
|
|
|
|
|
Sigmatropic rearrangements
|
|
|
|
|
|
On the question of the molecular mechanism of N-nitropyrazoles rearrangement
Jasinski R.
Chemistry of Heterocyclic Compounds, 56, 1210 (2020) |
|
|
|
|
|
|
Understanding the molecular mechanism rearrangement of internal nitronic ester into nitronorbornene in the light of MEDT study
Kacka-Zych A.
Molecules, 24, 462 (2019) |
|
|
|
|
|
|
A DFT computational study on the molecular mechanism of the nitro group migration in the product derived from 3-nitro-2-(trifluoromethyl)-2H-chromene and 2-(1-phenylpropylidene)malononitrile
Lapczuk-Krygier A., Korotaev V.Yu., Barkov A.Yu., Sosnovskikh V.Yu., Jasinska E., Jasinski R.
Journal of Fluorine Chemistry, 168, 236-239 (2014) |
|
|
|
|
|
|
Thermal eliminations
|
|
|
|
|
|
Unexpected molecular mechanism of trimethylsilyl bromide elimination from 2-(trimethylsilyloxy)-3-bromo-3-methyl-isoxazolidines
Kacka-Zych A., Jasinski R.
Theoretical Chemistry Accounts, 138, 81 (2019) |
|
|
|
|
|
|
A Molecular Electron Density Theory study of the Lewis acid – catalyzed decomposition reaction of nitroethyl benzoate using aluminium derivatives
Kacka-Zych A., Rios -Gutiérrez M., Domingo L.R.
Journal of Physical Organic Chemistry, 32, e3938 (2019) |
|
|
|
|
|
|
Understanding of the molecular mechanism of the phenylsulfenic acid elimination from nitroalkyl systems
Jasinski R.
Journal of Molecular Graphics and Modelling, 89, 109 (2019) |
|
|
|
|
|
|
Understanding the mechanism of the decomposition reaction of nitroethyl benzoate through the Molecular Electron Density Theory
Kacka-Zych A., Domingo L.R., Rios -Gutiérrez M., Jasinski R.
Theoretical Chemistry Accounts, 136, 129 (2017) |
|
|
|
|
|
|
A dramatic change of kinetic conditions and molecular mechanism of decomposition processes of nitroalkyl carboxylates catalyzed by ethylammonium cations
Kacka A., Jasinski R.
Computational and Theoretical Chemistry, 1104, 37-42 (2017) |
|
|
|
|
|
|
A DFT mechanistic study of thermal decomposition reactions of nitroethyl carboxylates: undermine of “pericyclic” insight
Kacka A., Jasinski R.
Heteroatom Chemistry, 27, 279-289 (2016) |
|
|
|
|
|
|
A new mechanistic insight on beta-lactam systems formation from 5-nitroisoxazolidines
Jasinski R.
RSC Advances, 5, 50070-50072 (2015) |
|
|
|
|
|
|
Molecular mechanism of thermal decomposition of fluoronitroazoxy compounds: DFT computational study
Jasinski R.
Journal of Fluorine Chemistry, 160, 29-33 (2014) |
|
|
|
|
|
|
Synthesis of conjugated nitroalkenes and their pharmaceutical applications
|
|
|
|
|
|
Novel Functionalized beta-Nitrostyrenes: Promising Candidates for New Antibacterial Drugs
Boguszewska-Czubara A., Kula K., Wnorowski A., Biernasiuk A., Popiolek P., Miodowski D., Demchuk O.M., Jasinski R
Saudi Pharmaceutical Journal, 27, 593-601 (2019) |
|
|
|
|
|
|
In the search for experimental and quantumchemical evidence for zwitterionic nature of (2E)-3-[4-(dimethylamino)phenyl]-2-nitroprop-2-enenitrile - an extreme example of donor-p-acceptor push-pull molecule
Jasinski R., Miroslaw B., Demchuk O.M., Babyuk D., Lapczuk-Krygier A.
Journal of Molecular Structure, 1108, 689-697 (2016) |
|
|
|
|
|
|
Novel synthesis scheme and in vitro antimicrobial evaluation of a panel of (E)-2-aryl-1-cyano-1-nitroethenes
Boguszewska-Czubara A, Lapczuk-Krygier A., Rykala K., Biernasiuk A., Wnorowski A, Popiolek l., Maziarka A., Hordyjewska A., Jasinski R.
Journal of Enzyme Inhibition and Medicinal Chemistry, 31, 900-907 (2016) |
|
|
|
|
|
|
Single crystal X-ray structure of (Z)-1-bromo-1-nitro-2-phenylethene
Lapczuk-Krygier A., Ponikiewski l.
Current Chemistry Letters, 4, 21-26 (2015) |
|
|
|
|
|
|
Ionic liquids and their application in organic synthesis
|
|
|
|
|
|
First example of stepwise, zwitterionic mechanism for bicyclo[2.2.1]hept-5-ene (norbornene) formation process catalyzed by the 1-butyl-3-methylimidazolium cations
Jasinski R.
Monatshefte fur Chemie - Chemical Monthly, 147, 1207-1213 (2016) |
|
|
|
|
|
|
Experimental and theoretical DFT study on synthesis of sterically crowded 2,3,3,(4)5-tetrasubstituted-4-nitroisoxazolidines via 1,3-dipolar cycloaddition reactions between ketonitrones and conjugated nitroalkenes
Jasinski R., Mroz K., Kacka A.
Journal of Heterocyclic Chemistry, 53, 1424-1429 (2016) |
|
|
|
|
|
|
A stepwise, zwitterionic mechanism for the 1,3-dipolar cycloaddition between (Z)-C-4-methoxyphenyl-N-phenylnitrone and gem-chloronitroethene catalyzed by 1-butyl-3-methylimidazolium ionic liquid cations
Jasinski R.
Tetrahedron Letters, 56, 532-535 (2015) |
|
|
|
|
|
|
Kinetic aspects of cycloaddition reactions
|
|
|
|
|
|
Kinetic aspects of [3+2] cycloaddition reactions between (E)-3,3,3-trichloro-1-nitroprop-1-ene and ketonitrones
Jasinski R., Mroz K.
Reaction Kinetics, Mechanisms and Catalysis, 116, 35-41 (2015) |
|
|
|
|
|
|
An experimental and theoretical study of the hetero Diels-Alder reactions between (E)-2-aryl-1-cyano-1-nitroethenes and ethyl vinyl ether: one-step or zwitterionic, two-step mechanism?
Jasinski R., Kubik M., Lapczuk-Krygier A., Kacka A., Dresler E., Boguszewska-Czubara A.
Reaction Kinetics, Mechanisms and Catalysis, 113, 333-345 (2014) |
|
|
|
|
|
|
